Fluctuating temperature outside superstatistics: Thermodynamics of small systems

نویسندگان

چکیده

The existence of fluctuations temperature has been a somewhat controversial topic in thermodynamics but nowadays it is recognized that they must be taken into account small, finite systems. Although for nonequilibrium steady states superstatistics becoming the \textit{de facto} framework expressing such fluctuations, some recent results put question idea as phase space observable. In this work we present and explore statistics describes part an isolated system, small enough to have well-defined uncertainties energy temperature, lacking superstatistical description. These motivate use so-called fundamental observable may relevant statistical description systems physical chemistry.

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ژورنال

عنوان ژورنال: Physica D: Nonlinear Phenomena

سال: 2022

ISSN: ['1872-8022', '0167-2789']

DOI: https://doi.org/10.1016/j.physa.2021.126665